Discrete Water Hexamers and Template-Assisted Molecular Recognition in an Elastic Zincophosphate Lattice
- 24 August 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (37) , 12794-12795
- https://doi.org/10.1021/ja054357k
Abstract
Water molecules and terephthalic acid, respectively, exist as a self-assembled monolayer of cyclic (H2O)6 clusters and (TA)∞ chiral chains between the zincophosphate sheets (in blue wires); the irremovable template H3tren3+ ions (in purple wires) are dynamic and could translate back and forth on the sheets during the conversion of the supramolecule contained in one another.Keywords
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