Asymmetric Cyclopentannelation. Chiral Auxiliary on the Allene
- 8 July 2000
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (16) , 2447-2450
- https://doi.org/10.1021/ol0001362
Abstract
An enantioselective variant of the synthesis of cross-conjugated cyclopentenones, based on d-glucose-derived chiral auxiliaries, is described. Minor modification of the method makes it applicable to the preparation of both enantiomeric series of products. Both enantiomers of the key intermediate in our roseophilin synthesis have been prepared.Keywords
This publication has 2 references indexed in Scilit:
- A Formal Total Synthesis of Roseophilin: Cyclopentannelation Approach to the Macrocyclic CoreOrganic Letters, 1999
- Some conversions of allenyl ethersRecueil des Travaux Chimiques des Pays-Bas, 1968