Dication salt of bis(ethylenedithio)tetrathiafulvalene: preparation and crystal structure of BEDT-TTF(ClO4)2
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1560-1562
- https://doi.org/10.1039/c39930001560
Abstract
Electrocrystallization of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) in an oxidizing solvent medium yields BEDT-TTF (ClO4)2, which is the first example of a salt in which BEDT-TTF is present only as the dication; bond length data from an X-ray structure determination of BEDT-TTF(ClO4)2 are used as a standard for assigning the +2 oxidation state to BEDT-TTF molecules in mixed-valent cation-radical salts.Keywords
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