Reactions of 2,6-Di-t-butyl-4-methylphenol with nitrogen dioxide; X-ray crystal structures of 2,6-Di-t-butyl-c-6-hydroxy-4-methyl-r-4,c-5-dinitrocyclohex-2-enone and 2,6-Di-t-butyl-4-methyl-r-4,c-5,c-6-trinitrocyclohex-2-enone
- 1 January 1983
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 36 (11) , 2339-2348
- https://doi.org/10.1071/ch9832339
Abstract
Reaction of 2,6-di-t-butyl-4-methylphenol (6) with nitrogen dioxide in benzene gives the trinitro ketone (11), but in cyclohexane gives both trinitro ketone (11) and the hydroxy dinitro ketone (12),in addition to the 4-nitro dienone (10). Some reactions and X-ray crystal structures of compounds (11) and (12) are described.Keywords
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