A simple, general synthesis of mixed d–f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(β-diketonate) luminophores linked by bis-diimine bridging ligands
- 11 October 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 21,p. 3925-3927
- https://doi.org/10.1039/b207832e
Abstract
Reaction of the mononuclear ‘complex ligands’ [Re(CO)3Cl(L)] [L = 2,2′-bipyrimidine (bpym) or 2,3-bis(2-pyridyl)pyrazine (bppz)] with a Ln(β-diketonate)3 unit affords the heterodinuclear complexes [Re(CO)3Cl(μ-bpym)Ln(fod)3] and [Re(CO)3Cl(μ-bppz)Ln(tta)3]; one member of each series has been structurally characterised.Keywords
This publication has 27 references indexed in Scilit:
- A kinetically inert and optically active CrIII partner in thermodynamically self-assembled heterodimetallic non-covalent d–f podatesJ. Chem. Soc., Dalton Trans., 2002
- Fluorescent photoinduced electron transfer (PET) sensing of anions using charge neutral chemosensorsElectronic supplementary data (ESI) available: 1H, 13C NMR for 1a–c and UV-Vis and NMR titration results for 1a are available as electronic supplementary information (ESI). See http://www.rsc.org/suppdata/cc/b1/b107608f/Chemical Communications, 2001
- Tunable Energy Transfer from Dicyanoaurate(I) and Dicyanoargentate(I) Donor Ions to Terbium(III) Acceptor Ions in Pure CrystalsInorganic Chemistry, 2000
- Porphyrin sensitization of circularly polarised near-IR lanthanide luminescence: enhanced emission with nucleic acid bindingChemical Communications, 2000
- Variation of Thermodynamic Parameters in the Adduct Formation of β-Diketonato Chelates with 1,10-Phenanthroline across the Lanthanoid SeriesBulletin of the Chemical Society of Japan, 1998
- Luminescent Labels—More than Just an Alternative to Radioisotopes?Angewandte Chemie International Edition in English, 1994
- Ruthenium(II) and Osmium(II) Bis(terpyridine) Complexes in Covalently-Linked Multicomponent Systems: Synthesis, Electrochemical Behavior, Absorption Spectra, and Photochemical and Photophysical PropertiesChemical Reviews, 1994
- Synthesis and characterization of rhenium(I) complexes bound to the bridging ligand 2,3-bis(2-pyridyl)pyrazineInorganic Chemistry, 1990
- Mixed-ligand complexes of trivalent lanthanide ions with .beta.-diketones and heterocyclic aminesInorganic Chemistry, 1982
- The crystal structure of tris(acetylacetonato)(1,10-phenanthroline) europium(III)Journal of Inorganic and Nuclear Chemistry, 1972