Facteurs stériques influençant la transposition de Wagner‐Meerwein des carbocations de type pinanyle
- 14 July 1976
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 59 (5) , 1894-1897
- https://doi.org/10.1002/hlca.19760590546
Abstract
Steric factors influencing Wagner‐Meerwein rearrangement of pinanyl carboniumions.The course of the Wagner‐Meerwein rearrangement of ions obtained by protonation of substituted α‐ or β‐pinenes is strongly dependent on the configuration of the substituents. The situation is complicated by the possibility of double bond isomerisation (α‐→β‐pinenes) before rearrangement. Simple rules for predicting the products are given.Keywords
This publication has 2 references indexed in Scilit:
- Rearrangements of pinane derivatives. Part I. Products of acid catalysed hydration of α-pinene and β-pineneJournal of the Chemical Society B: Physical Organic, 1971
- The NMR spectra and conformations of cyclic compounds-III: The conformations of some pinane derivativesMagnetic Resonance in Chemistry, 1969