Stark Spectroscopy of Polar Molecules Solvated in Liquid Helium Droplets
- 31 May 1999
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 82 (22) , 4480-4483
- https://doi.org/10.1103/physrevlett.82.4480
Abstract
Presented here are the first rotationally resolved Stark spectra of a polar molecule in a liquid. This high-resolution spectroscopy is made possible by the fact that superfluid liquid helium is extremely homogeneous. The results presented here show that the interactions between the molecule and the helium solvent result in a splitting very similar to that induced by the applied electric field, providing new insights into the nature of these interactions.Keywords
This publication has 27 references indexed in Scilit:
- Computer simulations of dipolar liquids near charged solid surfaces: electric-field-induced modifications of structure and dynamics of interfacial solventJournal of Molecular Structure: THEOCHEM, 1998
- Superfluidity Within a Small Helium-4 Cluster: The Microscopic Andronikashvili ExperimentScience, 1998
- STARK SPECTROSCOPY: Applications in Chemistry, Biology, and Materials ScienceAnnual Review of Physical Chemistry, 1997
- Vibrational spectroscopy of small water complexes embedded in large liquid helium clustersThe Journal of Chemical Physics, 1996
- High-Resolution Molecular Spectroscopy of van der Waals Clusters in Liquid Helium DropletsScience, 1996
- Rotationally Resolved Spectroscopy of Sin Liquid Helium Clusters: A Molecular Probe of Cluster TemperaturePhysical Review Letters, 1995
- Infrared-infrared double resonance spectroscopy of Ar-HF. Intermolecular state dependence of the dipole moment and vibrational predissociation in vHF = 2Chemical Physics Letters, 1994
- Infrared spectroscopy in highly quantum matrixes: vibrational spectrum of sulfur hexafluoride ((SF6)n=1,2) attached to helium clustersThe Journal of Physical Chemistry, 1993
- Vibrational spectroscopy of sulfur hexafluoride attached to helium clustersPhysical Review Letters, 1992
- Electric dipole moment and quadrupole hyperfine structure of OC–HCl and OC–DClThe Journal of Chemical Physics, 1983