Spectroscopic evidence for the formation of tri-µ-carbonyl-bis-[(η5-cyclopentadienyl)iron] on photolysis of bis[(dicarbonyl)(η5-cyclopentadienyl)iron] in low temperature matrices
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1022-1024
- https://doi.org/10.1039/c39830001022
Abstract
Photolysis of [{(η5-C5H5)Fe(CO)2}2] in CH4(12 K) and polyvinyl chloride film (12–77 K) matrices leads to the formation of a novel species proposed, on the basis of i.r. evidence including 13CO enrichment and u.v.– visible spectra, to be the CO-bridged dimer [(µ-CO)3{(η5-C5H5)Fe}2].Keywords
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