Intensity Distribution in the Sideband Spectrum of N $O_{3}^{-}$ in KI

22 December 1969

journal article
research article
Published by American Physical Society (APS) in Physical Review Letters

Vol. 23 (25) , 1455-1457
https://doi.org/10.1103/physrevlett.23.1455

Abstract

The 1400-

{cm}^{- 1}

absorption band of the nitrate impurity in potassium iodide shows at 4.2°K a considerable amount of fine structure. The intensity distribution of this fine structure is governed by the anharmonic coupling of the internal vibration of the nitrate ion with nearly unperturbed phonons. This distribution can be calculated satisfactorily by first-order perturbation theory.

Keywords

This publication has 10 references indexed in Scilit:

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Physical Review B, 1968
Lattice Vibrations of Solid Solutions; Infrared Absorption Spectra of Nitrate Ions in Alkali Halides
Physical Review B, 1968
One-Phonon Sideband of ${Sm}^{+ +}$ in KBr
Physical Review B, 1967
Sidebands in the Infrared Spectrum of $U$ Centers in Alkali Halides
Physical Review B, 1967
Sidebands of theU-Center-Induced Infrared Absorption Spectra of Alkali-Halide Crystals
Physical Review B, 1967
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Intensity Distribution in the Sideband Spectrum of NO3−in KI

Abstract

Keywords

Intensity Distribution in the Sideband Spectrum of N $O_{3}^{-}$ in KI