How does ionized N-methyl-O-methyl carbamate, CH3N(H)COOCH3+•, lose a methyl group? Unimolecular equilibration with two distonic isomers

Abstract
The unimolecular chemistry of the N-methyl-O-methyl carbamate radical cation CH3N(H)COOCH3•+, 1 has been studied by a variety of mass spectrometry based techniq...

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