Regio- and stereo-selective silaboration of alkynes catalysed by palladium and platinum complexes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2777-2778
- https://doi.org/10.1039/cc9960002777
Abstract
Addition of the silicon–boron bond across carbon–carbon triple bonds, i.e. silaboration is most effectively catalysed by a palladium(0)–tert-alkyl isocyanide complex to give (Z)-1-boryl-2-silyl alkenes with high regio- and stereo-selectivity, which are useful for synthesis of stereodefined alkenylsilanes.Keywords
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