Preparation and characterisation of a palladium–copper heterometallic complex and its catalytic activity towards oxidation of alkenes
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 1433-1434
- https://doi.org/10.1039/c39940001433
Abstract
Treatment of PdCl2(MeCN)2 and CuCl2 with pyrrolidin-2-one L gives a novel Pd–Cu heterometallic complex having a polymeric structure of [ClCu(L)4(µ-Cl)PdCl2·PdCl2]n which catalyses the oxidation of cyclohexene in ClCH2CH2Cl–MeOH.Keywords
This publication has 14 references indexed in Scilit:
- Palladium(II)-catalyzed oxygenation of the carbon-carbon double bond by molecular oxygen: A probe for involvement of a palladium hydroperoxide speciesJournal of Molecular Catalysis, 1992
- Palladium(II)-catalysed oxidation of carbon–carbon double bonds of allylic compounds with molecular oxygen; regioselective formation of aldehydesJournal of the Chemical Society, Chemical Communications, 1991
- New aspects of oxypalladation of alkenesAccounts of Chemical Research, 1990
- Synthesis, structure and reactivity of polymeric tetrabutylammonium di-.mu.-chlorobis(pentachlorophenyl)platinateargentate(1-), a novel chain polymeric Pt-Ag compound. Structure of (NBu4)[PtAgCl2(C6Cl5)2(PPh3)] and [Pt(C6Cl5)2(.mu.-Cl)2Ag2(PPh2Me)2]Inorganic Chemistry, 1986
- Synthetic Applications of the Palladium-Catalyzed Oxidation of Olefins to KetonesSynthesis, 1984
- Gaseous Chloride Complexes Containing Halogen BridgesAdvances in Inorganic Chemistry, 1983
- Ein Beitrag zu den Koordinationsverhältnissen in den gasförmigen MAI2Cl8‐Komplexen Das Spektrum von CoAl2ClnI8–n und die Kristallstruktur von PdAl2Cl8Zeitschrift für anorganische und allgemeine Chemie, 1981
- Palladium(II)-catalyzed asymmetric oxidative cyclization of 2-allylphenols in the presence of copper(II) acetate and molecular oxygen. Study of the catalysis of the Wacker-type oxidationJournal of the American Chemical Society, 1981
- Organic Synthesis with Palladium CompoundsPublished by Springer Nature ,1980
- Synthesis, X-ray crystal structure, and properties of a tetranuclear complex formed by oxidation of copper(I) chloride with molecular dioxygen in N-methylpyrrolidin-2-one. Isolation of a catalyst for the oxidative coupling of phenols by dioxygenJournal of the Chemical Society, Chemical Communications, 1978