THE HIGHLY STEREOSELECTIVE SYNTHESIS OF ETHYL GERANATE
- 5 July 1974
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 3 (7) , 705-708
- https://doi.org/10.1246/cl.1974.705
Abstract
The new method for the stereospecific synthesis of trisubstituted olefin was successfully applied to a highly stereoselective synthesis of 1,5-diene unit, demonstrating the preparation of ethyl geranate [3] starting from 3-methyl-2-butenyl bromide [1].Keywords
This publication has 3 references indexed in Scilit:
- Synthetic studies on insect hormones. VIII. Stereospecific synthesis of trisubstituted olefins from organocopper reagents and acetylenesJournal of the American Chemical Society, 1969
- Stereospecific synthesis of trisubstituted and tetrasubstituted olefins. Conjugate addition of dialkylcopper-lithium reagents to .alpha.,.beta.-acetylenic estersJournal of the American Chemical Society, 1969
- Unsaturated Macrocyclic Compounds. XIX.1 Linear and Cyclic Coupling Products Derived from trans-5-Decene-1,9-diyne. Attempted Syntheses of Cycloeicosadecaene and CyclotriacontapentadecaeneJournal of the American Chemical Society, 1961