Structures of toxic constituents in kraft mill caustic extraction effluents from 13C and 1H nuclear magnetic resonance

Abstract
Arguments based on 13C and 1H nmr spectroscopy are presented to elucidate the structures of 3,4,5- and 4,5,6-trichloroguaiacol, 12- and 14-monochlorodehydroabietic acid, and 12,14-dichlorodehydroabietic acid. These compounds were recently isolated and tentatively identified as major components toxic to fish in kraft mill caustic extraction effluents.

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