Models for polyurethane hydrolysis under moderately acidic conditions: A comparative study of hydrolysis rates of urethanes, ureas, and amides

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Abstract
The hydrolysis of model structures found in the hard blocks of polyurethanes has been studied under moderately acidic and neutral conditions. These include a series of N‐alkyl and N‐phenyl urethanes and ureas; for comparison purposes the corresponding amides and a carbonate ester based on bisphenol A were also studied. Of all functional groups the urethane was the most resistant to hydrolysis and the amide the most labile. Also, the N‐phenyl compounds were hydrolyzed faster than the corresponding alkyl derivatives. The carbonate ester underwent relatively rapid hydrolysis. Polyether containing polyurethanes, known to be relatively stable to hydrolysis, are discussed as to which polymer segments provide the weakest links under hydrolytic conditions.

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