Lewis Acid-Catalyzed Preparation of Bridge-head Adamantanoid Nitriles from their Corresponding Halides and Trimethylsilyl Cyanide
- 1 January 1985
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1985 (12) , 1140-1142
- https://doi.org/10.1055/s-1985-31453
Abstract
Bridge-head adamantyl and diamantyl nitriles 2 have been prepared in good yields by refluxing the corresponding halides 1 with trimethylsilyl cyanide and tin(IV) chloride in dichloromethane.Keywords
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