Influence of the trimethylsilyl group on the diastereoselectivity of an adjacent Claisen amide-acetal rearrangement
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 285-287
- https://doi.org/10.1039/c39830000285
Abstract
In contrast to their reactions with other (E)-allylic alcohols, the amide-acetals (1a, b) react with (E)-1-trimethylsilylpent-3-en-2-ol to give mixtures of product amides in which the threo-diasteroisomers marginally predominate.Keywords
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