Vibrational and electronic spectra of transition-metal carbonyl complexes. Part V. Solvent effects on the infrared spectra of the complexes (π-C5H5)Mn(CO)3and (π-C6Me6)Cr(Co)3
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2263-2264
- https://doi.org/10.1039/j19680002263
Abstract
Precise measurements of the i.r. spectra in the C–O stretching region of the compounds (π-C5H5)Mn(CO)3 and (π-C6Me6)Cr(CO)3 have been made in a range of solvents. The general behaviour is similar to that of the compound Co(CO)3NO and no evidence for a breakdown of the C3v selection rules could be observed.Keywords
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