Evidence for organoironcarbonylate anion formation in nucleophilic addition to tetracarbonyliron complexes of acrylate esters
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 428-429
- https://doi.org/10.1039/c39800000428
Abstract
Sequential addition of stabilized anions and alkyl iodides to tetracarbonyliron complexes of methyl acrylate and methyl crotonate affords products consistent with regiospecific generation and alkylation of an organoironcarbonylate anion intermediate.Keywords
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