Stereochemistry of desulphurisation and deoxygenation of oxophosphoranesulphenyl chlorides by trivalent phosphorus compounds
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 630-631
- https://doi.org/10.1039/c39740000630
Abstract
The ratio of desulphurisation to deoxygenation of oxophosphoranesulphenyl chlorides, >P(O)SCI, by trivalent phosphorus compounds depends on the nature of the PIII compounds and is accompanied by inversion of configuration at the chiral phosphorus atom of the sulphenyl chloride.Keywords
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