Transient Spectra and Photoreaction of 4-Methoxybenzoyloxyl Radical
- 1 August 1999
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 28 (8) , 805-806
- https://doi.org/10.1246/cl.1999.805
Abstract
An absorption maximum and a molar extinction coefficient of a transient in the laser flash photolysis of bis(4-methoxybenzoyl) peroxide were determined as 900 nm and 750 M−1cm−1, respectively. The comparison of products for the photolysis at 266 nm with and without 1064-nm pulse gave a solid evidence of 4-methoxybenzoyloxyl radical being responsible for the absorption.This publication has 7 references indexed in Scilit:
- A single-crystal neutron diffraction study of the temperature dependence of hydrogen-atom disorder in benzoic acid dimersJournal of the Chemical Society, Faraday Transactions, 1996
- Spectroscopic and kinetic characteristics of aroyloxyl radicals. 1. The 4-methoxybenzoyloxyl radicalJournal of the American Chemical Society, 1988
- A note on the total depletion method of measuring extinction coefficients of triplet-triplet transitionsThe Journal of Physical Chemistry, 1985
- Direct observation of benzoyloxyl radicals in photodecomposition of dibenzoyl peroxides with a time-resolved ESR techniqueJournal of the American Chemical Society, 1985
- Photolysis of Dibenzoyl Peroxide under Direct and Singlet Sensitized Irradiations. Mechanism for the Formation of the Geminate ProductBulletin of the Chemical Society of Japan, 1980
- Discrete Variational Xα Cluster Calculations. I. Application to Metal ClustersJournal of the Physics Society Japan, 1978
- Nonintegral Occupation Numbers in Transition Atoms in CrystalsPhysical Review B, 1969