Rotational rainbow scattering with large Δ j: Energy dependence of the anisotropy of the Na2–Ne, Ar interaction potential
- 1 March 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 86 (5) , 2680-2684
- https://doi.org/10.1063/1.452070
Abstract
Differential cross sections for rotational transitions in Na2–Ne, Ar collisions are measured up to very large Δj. It is shown that the energy dependent anisotropy ΔR(E) of the interaction potential can be determined from these data using simple classical relations of ΔR and the rainbow angle θR. Excellent agreement with ab initio data is demonstrated and underlines the usefulness of this concept.Keywords
This publication has 42 references indexed in Scilit:
- The rotational reflection principle in the direct photodissociation of triatomic molecules. Close-coupling and classical calculationsThe Journal of Chemical Physics, 1986
- Semiclassical analysis of rotational distributions in scattering and photodissociationThe Journal of Physical Chemistry, 1986
- Multiple collision rotational rainbows: Theory and experiment for Xe–CO2The Journal of Chemical Physics, 1985
- Multiple-collision rotational rainbow effect in molecule-surface scatteringThe Journal of Chemical Physics, 1983
- Anisotropies of the Na2–rare gas interaction potentials from angularly resolved inelastic scatteringThe Journal of Chemical Physics, 1983
- Theoretical investigation of rotational rainbow structures in X–Na2 collisions using CI potential surfaces. III. Rigid-rotor X = Ne scatteringThe Journal of Chemical Physics, 1982
- Rotational Energy Transfer in Direct Inelastic Surface Scattering: NO on Ag(111)Physical Review Letters, 1981
- Rotational rainbows: An IOS study of rotational excitation of hard-shell moleculesThe Journal of Chemical Physics, 1981
- Two-dimensional model of rotationally inelastic collisionsPhysical Review A, 1980
- State-to-state differential cross sections for rotationally inelastic scattering of Na2 by HeThe Journal of Chemical Physics, 1980