Mechanical studies of sol-gel transition: Universal behavior of elastic modulus
- 1 May 1987
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 35 (10) , 4329-4333
- https://doi.org/10.1103/physreva.35.4329
Abstract
The critical behavior of the shear modulus of agarose gel was studied as a function of concentration and temperature. Experimental evidence is presented that the elasticity exponent agrees with the conductivity exponent of a percolating resistor network. It is found that the value of the elasticity exponent of agarose gel is independent of the path to the phase boundary. These results strongly suggest that the elastic behavior of gel in the critical region can be explained by the scalar elasticity model of percolation theory irrespective of the mechanism of gelation.Keywords
This publication has 32 references indexed in Scilit:
- Mechanical measurements in the reaction bath during the polycondensation reaction, near the gelation thresholdMacromolecules, 1985
- Critical behavior of modulus of gelThe Journal of Chemical Physics, 1985
- Critical exponents in polymers: a sol-gel study of anionically prepared styrene-divinylbenzene copolymersMacromolecules, 1981
- Mechanical properties near gelation threshold, comparison with classical and 3d percolation theoriesPublished by Walter de Gruyter GmbH ,1981
- Scrutiny of the critical exponent paradigm, as exemplified by gelationPublished by Walter de Gruyter GmbH ,1981
- Polysaccharide shapes and their interactions - some recent advancesPublished by Walter de Gruyter GmbH ,1981
- The agarose double helix and its function in agarose gel structureJournal of Molecular Biology, 1974
- Spinodal Phase Separation in a Macromolecular Sol → Gel TransitionMacromolecules, 1974
- Structure-Property Relations of Thermoreversible Macromolecular HydrogelsMacromolecules, 1973
- Dynamic Mechanical Properties of Polyoxymethylene. IIJapanese Journal of Applied Physics, 1967