Abstract
The i.r. spectra of the new Me4N[M1{M2(CO)3-(π-C5H5}2] salts (M1= CuI or AgI, M2= Mo or W) imply that the M2–Ag–M2 bonding is linear, and that the [(π-C5H5)M2(CO)3] ligands are, at best, poor π-acceptors.

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