A functional model of manganese catalase. Mass spectrometric and visible spectral evidence for {MnIV(O)}2and MnIIMnIV(O) intermediates
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 882-884
- https://doi.org/10.1039/c39930000882
Abstract
A dinuclear manganese(II) complex [Mn2(L)(PhCO2)2(NCS)][L = 2,6-bis{N-[2-(dimethylamino)ethyl]iminomethyl}-4-methylphenolate(1–)] decomposes H2O2 catalytically indimethylformamidesolution; two oxomanganese(IV) species {MnIV(O)}2 and MnIIMnIV(O) are detected for the first time as intermediates in the H2O2 disproportionation reaction based on mass spectrometric and visible spectral studies.Keywords
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