Observation of Intramolecular C-H⋅⋅⋅F-C Contacts in Non‐Metallocene Polyolefin Catalysts: Model for Weak Attractive Interactions between Polymer Chain and Noninnocent Ligand
- 10 April 2003
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 42 (14) , 1628-1632
- https://doi.org/10.1002/anie.200219832
Abstract
No abstract availableKeywords
This publication has 29 references indexed in Scilit:
- Highly active ethylene polymerization catalysts based on titanium complexes having two phenoxy-imine chelate ligandsJournal of Molecular Catalysis A: Chemical, 2002
- Microstructure of Highly Syndiotactic “Living” Poly(propylene)s Produced from a Titanium Complex with Chelating Fluorine-Containing Phenoxyimine Ligands (an FI Catalyst)Macromolecular Rapid Communications, 2001
- Taming early transition metals: the use of polydentate amido-donor ligands to create well defined reactive sites in reagents and catalystsChemical Communications, 2000
- The Transition Metal Coordination Chemistry of Hemilabile LigandsPublished by Wiley ,1999
- Internal Fluorocarbon Coordination as a Tool for the Protection of Active Catalytic Sites: Experimental Characterization of the Zr···F−C Interaction in the Group 4 Metallocene(butadiene)/B(C6F5)3 Betaine Ziegler Catalyst SystemsJournal of the American Chemical Society, 1997
- Intramolecular Ion−Ion Interactions in Zwitterionic Metallocene Olefin Polymerization Catalysts Derived from “Tucked-In” Catalyst Precursors and the Highly Electrophilic Boranes XB(C6F5)2(X = H, C6F5)Journal of the American Chemical Society, 1997
- Formation of a Zirconocene–Betaine System by Electrophilic Substitution with B(C6F5)3 at a Cyclopentadienyl LigandAngewandte Chemie International Edition in English, 1996
- Bildung eines Zirconocen‐Betain‐Systems durch elektrophile Substitutionsreaktion mit B(C6F5)3 am CyclopentadienylligandenAngewandte Chemie, 1996
- .alpha. Agostic assistance in Ziegler-Natta polymerization of olefins. Deuterium isotopic perturbation of stereochemistry indicating coordination of an .alpha. carbon-hydrogen bond in chain propagationJournal of the American Chemical Society, 1990
- Carbon‐Hydrogen‐Transition Metal BondsPublished by Wiley ,1988