Molecular polarisability. A conformational study of some substituted arylcyclopropanes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 15,p. 2060-2063
- https://doi.org/10.1039/p29730002060
Abstract
The dipole moments and molar Kerr constants of the following substituted cyclopropanes have been measured in cyclohexane solution: 1,1-dichloro-2-p-chlorophenyl-2-methylcyclopropane, 1,1-dichloro-2-p-tolylcyclopropane, 1,1-dichloro-2-mesitylcyclopropane, 1,1-dichloro-2,2-diphenylcyclopropane, 1,1-dichloro-2,2-dimethyl-3-phenylcyclopropane, 1,1-dichloro-2,2,3,3-tetramethylcyclopropane, hexabromocyclopropane, 1,1-dibron phenylcyclopropane, 1,1-dibromo-2-p-tolylcyclopropane, 1,1-dibromo-2-p-bromophenylcyclopropane, and dibromo-2,2-diphenylcyclopropane. The data are analysed to deduce the preferred solution state conformation.Keywords
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