Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

16 November 2004

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 24,p. 2814-2815
https://doi.org/10.1039/b412338g

Abstract

The X-ray crystal structure of Gd₃N@C₈₀•Ni^II(OEP)•1.5(benzene) shows that the Gd₃N unit within the I_h C₈₀ cage is pyramidal, whereas Sc₃N@C₈₀, Sc₃N@C₇₈, Sc₃N@C₆₈, Lu₃N@C₈₀ and Sc₂ErN@C₈₀ have planar M₃N units.

Keywords

STRUCTURE
PYRAMIDALIZATION
GD3N
PLANAR
SC3N@C80
NIII
CRYSTAL
BENZENE

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