Tricarbonyl(η4-1.5-cümethylen-2.6-cümethylcyclooctan)eisen: photochemische Synthese und Struktur / Tricarbonyl(η4-1,5-dimethylene-2,6-dimethylcyclooctane)iron: Photochemical Synthesis and Structure
Open Access
- 1 March 1980
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 35 (3) , 360-365
- https://doi.org/10.1515/znb-1980-0319
Abstract
Extended photolysis of pentacarbonyliron in neat 2,3-dimethylbutadiene results in dimerization of the diene and formation of tricarbonyl(η4-1,5-dimethylene-2,6-dimethylcyclooctane) iron (1). The structure of complex 1 is characterized by a trigonal-bipyramidal geometry whereby the exocyclic double bonds of the diene ligand and one of the carbonyl groups lie exactly in the equatorial coordination plane.Keywords
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