Elimination Reactions of 2-Deoxy 2-C-Methyl Sugars : Application to the Synthesis of Methyl 2,3,4-Trideoxy-2,4-Di-C-Methyl-6-O-Triphenylmethyl α-D-Lyxo Hexopyranoside and its X Ray Crystal Structure
- 1 January 1984
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 3 (3) , 443-459
- https://doi.org/10.1080/07328308408057908
Abstract
A facile and regiospecific dehydration of 2-deoxy 2-C-methyl sugars using the triphenylphosphine-diethylazodicarboxylate reagent is reported. This reaction allowed us to prepare the title compound which is a crucial intermediate in the total synthesis of natural products. Its absolute configuration is firmly established by X Ray analysis.This publication has 24 references indexed in Scilit:
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