Substitution reactions of iodine pentafluoride: preparation and properties of methoxoiodine(V) fluorides
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 13,p. 1380-1384
- https://doi.org/10.1039/dt9740001380
Abstract
Methoxoiodine(V) fluorides, IF5 –n(OMe)n(n=1–4), and fluoro(methyl)silanes are formed from reactions of iodine pentafluoride with methoxomethylsilanes at 20 °C. The IF5 derivatives are labile and readily decompose with reduction of iodine(V). Although Me3SiF is formed from reactions of IF5 with other Me3SiX [X = Cl, SMe, OC(O)R, or Me] compounds, substituted derivatives of IF5 are not isolated because reduction occurs.Keywords
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