Quantum second virial coefficient of a two-dimensional Lennard-Jones gas
- 1 January 1965
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 9 (1) , 17-27
- https://doi.org/10.1080/00268976500100031
Abstract
We consider the equation of state of a dilute two-dimensional quantum degenerate gas at moderately high temperatures, and calculate the second virial coefficient assuming a Lennard-Jones function for the pair potential. The physical systems of interest are the mobile adsorption of gases on solid surfaces at low surface densities. The net Slater sum corrections to the classical B are smaller than for the three-dimensional case, whereas the effect of different particle statistics is enhanced. This leads to markedly different results in the two-dimensional problem.Keywords
This publication has 25 references indexed in Scilit:
- QUANTUM CORRECTIONS FOR THE ADSORPTION OF NEON ON GRAPHITIC CARBON1The Journal of Physical Chemistry, 1963
- High temperature adsorption and the determination of the surface area of solidsTransactions of the Faraday Society, 1962
- The One‐Dimensional PlasmaAdvances in Chemical Physics, 1962
- The Lennard-Jones 6–12 potential parameters of H2 and D2Physica, 1961
- Virial coefficients of hydrogen and deuterium at temperatures between −175°C and +150°C. Conclusions from the second virial coefficient with regards to the intermolecular potentialPhysica, 1960
- Preliminary Results from a Recalculation of the Monte Carlo Equation of State of Hard SpheresThe Journal of Chemical Physics, 1957
- Contribution to the quantum-mechanical theory of the equation of state and the law of corresponding states. Determination of the law of force of heliumPhysica, 1938
- The quantum theory of the non-ideal gas I. Deviations from the classical theoryPhysica, 1936
- Quantum Statistics of Almost Classical AssembliesPhysical Review B, 1933
- The Quantum Theory of the Equation of StatePhysical Review B, 1931