Transport properties of mesomorphic syndiotactic polystyrene

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Abstract
Amorphous syndiotactic polystyrene (sPS) films were annealed at 110° and 115°C for 24 h. The annealing at the higher temperature produced the mesomorphic form of sPS, characterized by conformational order, as shown both by the presence of the zigzag band in the infrared spectrum and by the presence of characteristic peaks in the x-ray diffractogram. The crystalline form was not formed at the investigated temperatures. Differential scanning calorimetry of the mesomorphic sample shows that the transformation of the mesophase into the crystalline phase occurs during the heating run. The transport properties of dichloromethane show that the mesophase is impermeable to the vapors at low activity and becomes permeable at higher activities. At low activity it is therefore possible to derive the fraction of impermeable phase, which corresponds to the fraction of mesophase. This fraction was about 50%.