Shifts in the X-ray K-absorption edge of copper due to chemical effects
- 1 December 1968
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 1 (6) , 1658-1661
- https://doi.org/10.1088/0022-3719/1/6/323
Abstract
We have investigated the K-absorption edge of copper in the metal and its compounds. It is found that owing to chemical combination the K-absorption edge of copper is, in general, shifted towards the high-energy side by 2-10 ev. However, in the case of Cu2O the shift is small and towards the low-energy side. A white line at the absorption edge has been detected for CuO, CuCO3, Cu[CH3COO]2 and Cu3[Fe(CN)6]2.Keywords
This publication has 10 references indexed in Scilit:
- Chemical effects in X-ray K absorption spectra of arsenicJournal of Physics C: Solid State Physics, 1968
- New Approach to Structure Studies in Organic ChemistryNature, 1967
- Electronic Band Structure of Solids by X-Ray SpectroscopyReviews of Modern Physics, 1959
- Chemical Shift Effect in Inner Electronic Levels of Cu Due to OxidationPhysical Review B, 1958
- "Thickness Effect" in Absorption Spectra near Absorption EdgesPhysical Review B, 1957
- XX. Note on the electronic structure of the transition metalsJournal of Computers in Education, 1953
- The Soft X-Ray Valence Band Spectra and the Heat of Formation of Chemical Compounds and AlloysPhysical Review B, 1950
- CXVI. The interpretation of X-ray absorption spectra of solidsJournal of Computers in Education, 1949
- On the empty electron bands of lowest energy of the transition metals Mn and Fe and their oxidesPhysica, 1948
- The Widths of the-Series Lines and of the Energy Levels of Au(79)Physical Review B, 1934