Resonant inverse photoemission of Bi2Ca1+xSr2xCu2O8+y and YBa2Cu3O7x, unoccupied oxygen states, and plasmons

Abstract
Inverse photoemission studies of the unoccupied states of Bi2Ca1+xSr2xCu2O8+y, with and without 10% Pb substitution for Bi, show a low density of states within 2 eV of the Fermi level and broad structures at 4, 9.6, and 12.6 eV that are associated with Bi 6p, Ca 3d, and Sr 4d empty-state bands. Plasmon losses are observed via their radiative decay at photon energies of 15 and 21.2 eV. Resonant inverse photoemission, using incident electron energies that excite O 2s shallow core levels, enhances emission from the unoccupied O 2p levels. Resonance results for YBa2Cu3O7x and Bi2Ca1+xSr2xCu2O8+y show similar oxygen distributions near EF.