EXTRACTION BY N,N'-TETRAALKYLMALONAMIDES II.
- 1 October 1987
- journal article
- research article
- Published by Taylor & Francis in Solvent Extraction and Ion Exchange
- Vol. 5 (5) , 877-893
- https://doi.org/10.1080/07366298708918598
Abstract
Suitable N.N'-tetraalkylmalonamldes for Am(III) extraction from concentrated HNO3 aqueous liquors have been selected. Extraction mechanisms of Eu(III) and Am(III) by NN'-dlmethyldioctylmalonamide (DMDOMA) have been investigated. The distributions ratios of Am(III) and Eu(III) between 1M DMDOMA in t-butylbenzene and per chloric acid are higher than those obtained In nitrate media. Extraction data for Pu)IV), U(VI), Fe(III), Zr(IV) are reported. From these results It can be concluded that the NN'-dlmethyldlal-kylmalonamldes are good extractants for the actinides contained in the radioactive wastes.Keywords
This publication has 9 references indexed in Scilit:
- Mecanisme d'extraction des ions uranium(VI) par les N,N-DialkylamidesJournal of the Less Common Metals, 1986
- EXTRACTION OF Am FROM NITRIC ACID BY CARBAMOYL-PHOSPHORYL EXTRACTANTS: THE INFLUENCE OF SUBSTITUENTS ON THE SELECTIVITY OF Am OVER Fe AND SELECTED FISSION PRODUCTSSolvent Extraction and Ion Exchange, 1986
- THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT*Solvent Extraction and Ion Exchange, 1985
- The Extraction of Selected Transplutonium(III) and Lanthanide(III) Ions by Dihexyl-N, N-diethylcarbamoylmethylphosphonate from Aqueous Nitrate MediaSeparation Science and Technology, 1981
- Solvent Extraction Chemistry and Kinetics of ZirconiumSeparation Science and Technology, 1980
- Application of N, N-Dialkyl Aliphatic amides in the Separation of Some ActinidesSeparation Science and Technology, 1980
- Adducts between some lanthanide nitrates and perchlorates and N,N,N′,N′-tetramethylmalonamide(TMMA)Journal of Inorganic and Nuclear Chemistry, 1972
- Bidentate organophosphorus compounds as extractants—IJournal of Inorganic and Nuclear Chemistry, 1963
- EFFECTS OF STRUCTURE OF N,N-DISUBSTITUTED AMIDES ON THEIR EXTRACTION OF ACTINIDE AND ZIRCONIUM NITRATES AND OF NITRIC ACID1The Journal of Physical Chemistry, 1960