A novel allyl-ruthenium cluster: the σ-1,3-h2-π-1,2,3-h3-cyclododeca-1,6,9-trienyl ligand as a five-electron donor
- 1 January 1970
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 12,p. 735-736
- https://doi.org/10.1039/c29700000735
Abstract
Reactions of cyclododeca-1,5,9-trienes with Ru3(CO)12 lead to dehydrogenation and isomerisation with the formation of four cluster complexes: in the major product, HRu3(CO)9(C12H15), the monocyclic ligand is attached to the cluster by an unusual allylic bonding arrangement involving only three carbon atoms.Keywords
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