Optical activity of the 260 nm transition of chiral thiirans

1 January 1977

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2

No. 9,p. 1105-1111
https://doi.org/10.1039/p29770001105

Abstract

The optical activity of the 260 nm n→σ* transition of chiral thiirans is rationalized in terms of a dynamic coupling mechanism. From the treatment a symmetry rule is derived.

Keywords

TREATMENT
SYMMETRY
RATIONALIZED
NM TRANSITION
TRANSITION OF CHIRAL
OPTICAL ACTIVITY
THIIRANS