Effective 1,7-asymmetric induction in reactions between 6-hydroxyallylstannanes and aldehydes promoted by tin(IV) bromide
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 283-284
- https://doi.org/10.1039/c39940000283
Abstract
Transmetallation of tributyl[(6R)-6-hydroxyhept-2-enyl]stannane 7 by tin(IV) bromide generates an allyltin tribromide which reacts with aldehydes to give 1-substituted 1,7-dihydroxyoct-3-enes with effective 1,7-asymmetric induction.Keywords
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