The preferred conformation of α-fluoroamides
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 11,p. 2409-2411
- https://doi.org/10.1039/a907452j
Abstract
X-Ray structures of two α-fluoroamide derivatives show the OC–C–F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol–1) potential minimum.Keywords
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