Deuterium isotope effects in a triply degenerate cyclopropylethyl cation
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 496-498
- https://doi.org/10.1039/c39850000496
Abstract
The equilibrium isotope effect on the degenerate rearrangement of the 1-(2,3-dimethylclopropyl)ethyl cation is compared with theoretical and other experimental data and the implications for the interpretation of kinetic isotope effects and for the investigation of hyperco-ordinated carbocations are discussed.Keywords
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