Associating behaviour of pure polar liquids: dielectric properties of n-valeric acid
- 14 May 1984
- journal article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 17 (5) , 1007-1012
- https://doi.org/10.1088/0022-3727/17/5/014
Abstract
The results are reported of a study of the associating behaviour of n-valeric acid, made through the determination of its dielectric properties. The values obtained for the correlation factor between molecular pairs, which exist due to hydrogen bonds, suggest the presence of a high degree of dimerisation in the liquid phase, with the number of dimers decreasing with increasing temperature.Keywords
This publication has 12 references indexed in Scilit:
- Dielectric properties of pure polar liquids: associating behaviour of erucic acidJournal of Physics D: Applied Physics, 1983
- Far infrared studies of hydrogen bonding in carboxylic acids—IISpectrochimica Acta Part A: Molecular Spectroscopy, 1969
- The crystal structure of valeric acidActa Crystallographica, 1962
- Stoichiometric Investigations of the Liquid State. V. Vaporization Phenomenon of Associated LiquidsBulletin of the Chemical Society of Japan, 1957
- Stoichiometric Investigations of the Liquid State IV. Viscosity of Associated LiquidBulletin of the Chemical Society of Japan, 1957
- General theory of the static dielectric constantTransactions of the Faraday Society, 1948
- POLARIZATION MEASUREMENTS ON CARBOXYLIC ACIDS IN DILUTE SOLUTION IN NON‐POLAR SOLVENTSAnnals of the New York Academy of Sciences, 1940
- The Dielectric Polarization of Polar LiquidsThe Journal of Chemical Physics, 1939
- Electric Moments of Molecules in LiquidsJournal of the American Chemical Society, 1936
- THE DIELECTRIC POLARIZATION OF LIQUIDS. VIII. ACETIC AND BUTYRIC ACIDSJournal of the American Chemical Society, 1930