Alpha- and beta-migratory insertion and elimination processes for alkyl complexes of permethyl-scandocene and permethyltantalocene
- 1 July 1987
- journal article
- Published by Elsevier in Journal of Molecular Catalysis
- Vol. 41 (1-2) , 21-39
- https://doi.org/10.1016/0304-5102(87)80017-2
Abstract
No abstract availableThis publication has 11 references indexed in Scilit:
- .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bondsJournal of the American Chemical Society, 1987
- Hydrido methylidene, hydrido vinylidene, hydrido oxo, and hydrido formaldehyde derivatives of bis(pentamethylcyclopentadienyl)tantalumJournal of the American Chemical Society, 1986
- Isotope effects in arene carbon-hydrogen bond activation by [(C5Me5)Rh(PMe3)]Journal of the American Chemical Society, 1986
- Bent-sandwich derivatives of tantalum bearing one or two pentamethylcyclopentadienyl ligandsOrganometallics, 1986
- Kinetics and mechanism of the insertion of olefins into transition metal-hydride bondsJournal of the American Chemical Society, 1985
- Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalystJournal of the American Chemical Society, 1985
- Some aspects of the chemistry of alkyl and hydride derivatives of permethylscandocenePublished by Walter de Gruyter GmbH ,1984
- Hydrogen-transfer reactions which generate new imine, imido, and trimethylenemethane complexes of tantalumJournal of the American Chemical Society, 1983
- .alpha.-Hydride vs. .beta.-hydride elimination. An example of an equilibrium between two tautomersOrganometallics, 1982
- Migratory insertion reactions of carbenes. Kinetics and mechanism of migratory insertion reactions of zirconoxy carbene complexes of niobocene hydride and alkylsJournal of the American Chemical Society, 1981