Regioselectivity of selenoxide elimination: synthesis of the cyclohexenediol fragment of non-aromatic β-milbemycins
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 880-881
- https://doi.org/10.1039/c39870000880
Abstract
Whereas selenoxide elimination from the hydroxyselenide (6) gave predominantly exocyclic elimination, preferred endocyclic elimination was observed from the corresponding ketone (5), and was applied to a synthesis of the cyclohexenediol fragment of the non-aromatic β-milbemycins.Keywords
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