Evidence for an anionic intermediate in the mechanistic pathway of the oxidative addition reaction of [(cyclo-octadiene)IrCl(PEtPh2)] with hydrochloric acid

1 January 1977

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 23,p. 845-846
https://doi.org/10.1039/c39770000845

Abstract

[(cod)IrCl(PEtPh₂)] reacts with HCl to form the oxidative addition product [(cod)IrHCl₂(PEtPh₂)]via the intermediate [(cod)IrCl₂(PEtPh₂)]^–(cod = cyclo-octadiene).

Keywords

ANIONIC INTERMEDIATE
REACTS
IRHCL2
IRCL2
HYDROCHLORIC
EVIDENCE
OCTADIENE