Atropisomeric sulphur compounds in organic synthesis: generation and reactions of the carbanions of dinaphtho[2,1-d:1′,2′-f][1,3]dithiepine and its oxides
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 411-412
- https://doi.org/10.1039/c39890000411
Abstract
Oxidation of dinaphtho[2,1-d:1′,2′-f][1,3]dithiepine (2) gives a single diastereoisomeric sulphoxide (1) which reacts diastereospecifically with electrophiles at variance with the unoxidized substrate (2) and other combinations of oxides (4),(6), and (7) which afford diastereoisomeric mixtures of products.Keywords
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