Unexpected formation of 1,3-diselenetanes from the reaction of camphor enolate with selenium
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 515-516
- https://doi.org/10.1039/c39940000515
Abstract
The reaction of camphor enolate with selenium in THF affords mainly the corresponding diselenide, whereas a mixture of two isomeric 1,3-diselenetanes–one of which is characterized by X-ray crystallography–is produced in the presence of methyl iodide.Keywords
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