A study of HOCO resonances in the OH+CO→CO2+H reaction
- 15 August 1994
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 101 (4) , 2779-2784
- https://doi.org/10.1063/1.467593
Abstract
Quasibound states of the HOCO intermediate in the reaction OH+CO→H+CO2 are studied by means of the stabilization method. A reduced‐dimensionality model is used. The calculated resonance positions and lifetimes agree well with previous quantum scattering calculations. Most of the quasibound states can be assigned approximately to a vibrational excitation in the higher frequency OH vibration and different progressions in the HO–CO stretching mode. Some interesting mode‐specific effects in the dynamics of the unimolecular decay are predicted.Keywords
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