Notizen: Gold Complexes with Selenium Ligands, V. Synthesis and Crystal Structure of [(Ph3PAu)2Se(p-C6F4Cl)]+SbF6 -

Abstract
The binuclear complex [(Ph3PAu)2Se(p-C6F4Cl)]+SbF6 - was prepared from Ph3PAuCl and (p-C6F4Cl)2Se2 in the presence of AgSbF6. The crystal structure shows a short intramolecular gold-gold interaction, which leads to an extreme distortion in the coordination geometry at selenium.

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