Ring-Closing Olefin Metathesis and Radical Cyclization as Competing Pathways
- 17 January 2004
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 69 (4) , 1421-1424
- https://doi.org/10.1021/jo0353942
Abstract
First and second generation Grubbs' catalyst mediate under otherwise identical conditions two different cyclization modes with high selectivity: a ring-closing metathesis and an atom-transfer radical addition (ATRA) pathway.Keywords
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